Nentjes beat Ross Smith 5-3 in the deciding final contest of the fourth night of the new tournament, which sees players taking part from home via video link which is screened live on the internet.
Ashton, the first woman to get a PDC Tour Card through qualifying school, fell 5-1 to Smith in the opening match.
The four-time BDO women's world champion had the chance to take Nentjes to a final leg but twice missed double top and the Dutchman wrapped up a 5-3 win with his last effort at double five to follow his earlier 5-4 triumph against former Players Championship event winner Mickey Mansell.
Northern Irishman Mansell beat Smith 5-3 to keep himself in the running but Ashton extinguished his chances as she signed off with a 5-3 victory.
The Bolton thrower went 3-0 and then 4-2 up before throwing away a good position after hitting 180 early in the seventh leg.
But she hit double 19 at the first attempt to leave Nentjes and 2019 UK Open quarter-finalist Smith to face off for the group.
The 21-year-old Dutchman got off to a flying start in the decider and kept his nerve after a fightback from Smith to join Dave Chisnall, Luke Woodhouse and Jamie Lewis as group winners.
Nentjes said: "I wasn't expecting to play this well but I got the match feeling again, in my home environment, and I was just hitting it. Can we play like this all the time?"
- Each night’s action begins at 1930 BST, and will include webcam footage of each player and their dart board, live score graphics and commentary from Dan Dawson. All PDC Home Tour action will be broadcast live on PDCTV for FREE to ALL registered PDCTV users, regardless of whether you have a paid or free membership
PDC Home Tour Darts: Fixtures, Results & Tables
Play begins at 1930 BST each night
Best of nine legs
Click here for Sky Bet odds
GROUP 1: Friday April 17
- Peter Wright 5-4 Peter Jacques
- Jamie Lewis 3-5 Niels Zonneveld
- Peter Jacques 5-2 Niels Zonneveld
- Peter Wright 1-5 Jamie Lewis
- Jamie Lewis 5-4 Peter Jacques
- Niels Zonneveld 1-5 Peter Wright
CLICK HERE FOR FULL ROUND-UP
GROUP STANDINGS
- Jamie Lewis (Q) P 3 W 2 L 1 Leg Diff +3 Pts 4
- Peter Wright P 3 W 2 L 1 Leg Diff +1 Pts 4
- Peter Jacques P 3 W 1 L 2 Leg Diff +1 Pts 2
- Niels Zonneveld P 3 W 1 L 2 Leg Diff -5 Pts 2
GROUP 2: Saturday April 18
- Gerwyn Price 5-2 Rowby-John Rodriguez
- Luke Woodhouse 5-2 Ted Evetts
- Rowby-John Rodriguez 3-5 Ted Evetts
- Gerwyn Price 0-5 Luke Woodhouse * WOODHOUSE HITS NINE-DARTER
- Luke Woodhouse 5-2 Rowby-John Rodriguez
- Ted Evetts 2-5 Gerwyn Price
CLICK HERE FOR FULL ROUND-UP
GROUP STANDINGS
- Luke Woodhouse (Q) P 3 W 3 L 0 Leg Diff +11 Pts 6
- Gerwyn Price P 3 W 2 L 1 Leg Diff +1 Pts 4
- Ted Evetts P 3 W 1 L 2 Leg Diff -4 Pts 2
- Rowby-John Rodriguez P 3 W 0 L 3 Leg Diff -8 Pts 0
GROUP 3: Sunday April 19
- Dave Chisnall 5-2 Scott Waites
- Jan Dekker 4-5 Jonathan Worsley
- Scott Waites 5-1 Jonathan Worsley
- Dave Chisnall 5-0 Jan Dekker
- Jan Dekker 1-5 Scott Waites
- Jonathan Worsley 1-5 Dave Chisnall
CLICK HERE FOR FULL ROUND-UP
GROUP STANDINGS
- Dave Chisnall P 3 W 3 L 0 Leg Diff +12 Pts 6
- Scott Waites P 3 W 2 L 1 Leg Diff +5 Pts 4
- Jonathan Worsley P 3 W 1 L 2 Leg Diff -7 Pts 2
- Jan Dekker P 3 W 0 L 3 Leg Diff -10 Pts 0
GROUP 4: Monday April 20
- Ross Smith 5-1 Lisa Ashton
- Mickey Mansell 4-5 Geert Nentjes
- Lisa Ashton 3-5 Geert Nentjes
- Ross Smith 3-5 Mickey Mansell
- Mickey Mansell 3-5 Lisa Ashton
- Geert Nentjes 5-3 Ross Smith
GROUP STANDINGS
- Geert Nentjes P 3 W 3 L 0 Leg Diff +5 Pts 6
- Ross Smith P 3 W 1 L 2 Leg Diff 0 Pts 2
- Mickey Mansell P 3 W 1 L 2 Leg Diff -1 Pts 2
- Lisa Ashton P 3 W 1 L 2 Leg Diff -4 Pts 2
GROUP 5: Tuesday April 21
- Luke Humphries v Nick Kenny
- Devon Petersen v Joe Murnan
- Nick Kenny v Joe Murnan
- Luke Humphries v Devon Petersen
- Devon Petersen v Nick Kenny
- Joe Murnan v Luke Humphries
GROUP STANDINGS
- Luke Humphries P 0 W 0 L 0 Leg Diff +0 Pts 0
- Nick Kenny P 0 W 0 L 0 Leg Diff +0 Pts 0
- Devon Petersen P 0 W 0 L 0 Leg Diff +0 Pts 0
- Joe Murnan P 0 W 0 L 0 Leg Diff +0 Pts 0
GROUP 6: Wednesday April 22
- James Wade v Adrian Gray
- Ryan Searle v Andy Boulton
- Adrian Gray v Andy Boulton
- James Wade v Ryan Searle
- Ryan Searle v Adrian Gray
- Andy Boulton v James Wade
GROUP STANDINGS
- James Wade P 0 W 0 L 0 Leg Diff +0 Pts 0
- Adrian Gray P 0 W 0 L 0 Leg Diff +0 Pts 0
- Ryan Searle P 0 W 0 L 0 Leg Diff +0 Pts 0
- Andy Boulton P 0 W 0 L 0 Leg Diff +0 Pts 0
GROUP 7: Thursday April 23
- Gabriel Clemens v Ryan Meikle
- Jelle Klaasen v Gavin Carlin
- Ryan Meikle v Gavin Carlin
- Gabriel Clemens v Jelle Klaasen
- Jelle Klaasen v Ryan Meikle
- Gavin Carlin v Gabriel Clemens
GROUP STANDINGS
- Gabriel Clemens P 0 W 0 L 0 Leg Diff +0 Pts 0
- Ryan Meikle P 0 W 0 L 0 Leg Diff +0 Pts 0
- Gavin Carlin P 0 W 0 L 0 Leg Diff +0 Pts 0
- Jelle Klaasen P 0 W 0 L 0 Leg Diff +0 Pts 0
GROUP 8: Friday April 24
- Jonny Clayton v Adam Hunt
- Richard North v David Pallett
- Adam Hunt v David Pallett
- Jonny Clayton v Richard North
- Richard North v Adam Hunt
- David Pallett v Jonny Clayton
GROUP STANDINGS
- Jonny Clayton P 0 W 0 L 0 Leg Diff +0 Pts 0
- Adam Hunt P 0 W 0 L 0 Leg Diff +0 Pts 0
- Richard North P 0 W 0 L 0 Leg Diff +0 Pts 0
- David Pallett P 0 W 0 L 0 Leg Diff +0 Pts 0
GROUP 9 ONWARDS YET TO BE ANNOUNCED
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